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On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)

Terrett, Richard; Cavigliasso, German; Stranger, Robert; Yates, Brian F


The calix[4]arene niobium(iii) complex ([L]Nb-NN-Nb[L] where [L] = p-tert-butylcalix[4]arene), reported to bind N2 in a μ2-linear dimeric capacity and to activate the N2 triple bond to 1.39 Å, corresponding to the longest N2 bond known in the end-on coo

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c1dt11091h


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