On the unprecedented level of dinitrogen activation in the calix[4]arene complex of Nb(III)
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Terrett, Richard; Cavigliasso, German; Stranger, Robert; Yates, Brian F
Description
The calix[4]arene niobium(iii) complex ([L]Nb-NN-Nb[L] where [L] = p-tert-butylcalix[4]arene), reported to bind N2 in a μ2-linear dimeric capacity and to activate the N2 triple bond to 1.39 Å, corresponding to the longest N2 bond known in the end-on coo
Collections | ANU Research Publications |
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Date published: | 2011 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/62442 |
Source: | Dalton Transactions |
DOI: | 10.1039/c1dt11091h |
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