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New insights into 1,2,4-trioxolane stability and the crucial role of ozone in promoting polymer degradation

Lee, Zhong (Richmond); Coote, Michelle

Description

Quantum chemical calculations reveal that ozone is capable of instigating a series of degradative processes in poly(methyl methacrylate). The crux lies in the self-decomposition of 1,2,4-trioxolane, which undergoes a spin intersystem crossing process and

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/62376
Source: Physical Chemistry Chemical Physics
DOI: 10.1039/C3CP52863D

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