Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand.
A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh 2]-, with palladium appears to be best described as PdI-SnIII or Pd0-SnIV.
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|Source:||European Journal of Inorganic Chemistry|
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