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Dichotomy between palladium(II)-tin(II) and palladium(0)-tin(IV) in complexes of a Sn,As-based chelate ligand.

Mirzadeh, Nedaossadat; Bennett, Martin; Wagler, Jorg; Wachtler, Erik; Gerke, Birgit; Pottgen, Rainer; Bhargava, Suresh Kumar

Description

A dinuclear Pd-Sn bonded complex is reported, in which the interaction of the formally tin(II)-based ligand, [2-MeBrSnC6F4AsPh 2]-, with palladium appears to be best described as PdI-SnIII or Pd0-SnIV.

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/61981
Source: European Journal of Inorganic Chemistry
DOI: 10.1002/ejic.201300115

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