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A chemoenzymatic total synthesis of the protoilludane aryl ester (+)-Armillarivin

Schwartz, Brett; Matousova, Eliska; White, Richard; Banwell, Martin; Willis, Anthony


The title natural product, 1, has been synthesized in 20 steps from the enantiomerically pure cis-1,2-dihydrocatechol 2, itself obtained through the whole-cell biotransformation of toluene. The pivotal steps in the reaction sequence involve a Diels-Alder

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Organic Letters
DOI: 10.1021/ol400583c


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