Mixed-metal cluster chemistry: 32. Synthesis, structure, and reactivity of a trimetallic molybdenum-iridium carbonyl cluster possessing a μ 3 -η 2 -benzyne ligand
Randles , Michael; Gupta, Vivek; Simpson, Peter; Moxey, Graeme; Criddle, Alan; Stranger, Robert; Cifuentes, Marie; Humphrey, Mark
Description
The reaction of Mo2Ir2(μ-CO)3(CO) 7(η5-C5H5)2 and Ir(CCCH2OH)(CO)(PPh3)3 in refluxing toluene gives the molybdenum-iridium cluster MoIr2(μ3- η2-C6H4)(μ-PPh2)(μ-CO) 2(CO)4(η5-C5H5) (1) in low yield. Mo2Ir2(μ-CO)3(CO) 6(PPh3)(η5-C5H5) 2 (2) is a po
Collections | ANU Research Publications |
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Date published: | 2013 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/61842 |
Source: | Polyhedron |
DOI: | 10.1016/j.poly.2012.07.018 |
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