Organoactinides promote the dimerization of aldehydes: Scope, kinetics, thermodynamics, and calculation studies
Surprising catalytic activities have been found for the actinide complexes Cp*2ThMe2 (1), Th(NEtMe)4 (2), and Me2SiCp″2Th(C4H9)2(3) toward oxygenated substrates. During the catalytic dimerization of benzaldehydes to their corresponding esters, complexes
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|Source:||Journal of the American Chemical Society|
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