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Organoactinides promote the dimerization of aldehydes: Scope, kinetics, thermodynamics, and calculation studies

Sharma, Manab; Andrea, Tamar; Brookes, Nigel J; Yates, Brian F; Eisen, Moris S.

Description

Surprising catalytic activities have been found for the actinide complexes Cp*2ThMe2 (1), Th(NEtMe)4 (2), and Me2SiCp″2Th(C4H9)2(3) toward oxygenated substrates. During the catalytic dimerization of benzaldehydes to their corresponding esters, complexes

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/61781
Source: Journal of the American Chemical Society
DOI: 10.1021/ja105696p

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