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Carbon-carbon and carbon-chlorine bond formation on reaction of iodine(III) reagents with the bis(alkynyl)palladium(II) motif, and structural chemistry of trans -Pd(C≡C- o -Tol) 2 (PMe 2 Ph) 2 ] and trans -[PdCl(C≡C- o -Tol) 2 (PMe 2 Ph) 2 ]

Sharma, Manab; Canty, Allan; Gardiner, Michael G; Jones, Roderick C.

Description

Trans-di(ortho-tolylethynyl)bis(dimethylphenylphosphine)palladium(II) reacts above -20 °C with the iodonium reagent IPhCl2 to give predominantly o-Tol-CC-Cl, above 15 °C with IPh2(OTf) (OTf = triflate) to give o-Tol-CC-Ph and (o-Tol-CC)2 in ca. 3:1 rati

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/61772
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2011.01.018

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