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Binuclear intermediates in oxidation reactions: [{Me 3 SiC≡C)Me 2 (bipy)Pt-PtMe 2 (bipy)] + in the Oxidation of Pt II Me 2 (bipy) (bipy = 2,2'-Bipyridine) by IPh(C≡CSiMe 3 )(OTf) (OTf = Triflate)

Canty, Allan; Gardiner, Michael G; Jones, Roderick C.; Rodemann, Thomas; Sharma, Manab

Description

(Chemical Equation Presented) A study of the reaction of PtMe 2(bipy) with IPh(C≡CSiMe3)(OTf) at low temperature in acetone, leading to detection of the Pt-Pt-bonded cation [Pt 2Me4(C≡CSiMe3)(bipy)2]+, an intermediate in the oxidation of PtII to PtIV,

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/61738
Source: Journal of the American Chemical Society
DOI: 10.1021/ja902799u

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