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Rhodium(I) carbonyl complexes of mono selenium functionalized bis(diphenylphosphino)methane and bis(diphenylphosphino)amine chelating ligands and their catalytic carbonylation activity

Dutta, Dipak K.; Woollins, J Derek; Slawin, Alexandra M. Z.; Konwar, Dilip; Sharma, Manab; Bhattacharyya, Pravat; Aucott, Stephen M.


The chelate complexes of the types (1) and (2) have been synthesized and characterized by IR and NMR spectroscopy. The lower shift of the ν(P-Se) bands and downfield shift of the31P-{1H}NMR signals for both P(III) and P(V) atoms in 1 and 2 compared to th

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2005.11.069


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