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Dinitrogen metal complexes with a strongly activated N-N bond: a computational investigation of [(Cy 2 N) 3 Nb-(μ-NN)-Nb(NCy 2 ) 3 ] and related [Nb-(μ-NN)-Nb] systems

Cavigliasso, German; Stranger, Robert; Yates, Brian F

Description

The structural and bonding properties of the dinitrogen-bridged diniobium [(Cy2N)3Nb(μ-NN)Nb(NCy2)3] complex experimentally characterized by Berno and Gambarotta, which exhibits a strongly activated N-N bond of 134 pm, have been explored using density fu

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
URI: http://hdl.handle.net/1885/61664
Source: Dalton Transactions
DOI: 10.1039/C2DT31845H

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