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Reactivities of amino acid derivatives toward hydrogen abstraction by Cl• and OH•

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Chan, Bun; O'Reilly, Robert J; Easton, Christopher; Radom, Leo

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In recent computational studies of hydrogen-atom abstraction from amino acid derivatives, two distinct rationalizations have been put forward for the relative inertness of the α-C-H. Of these, the proposal that the inertness is due to a "kinetic trap" as

dc.contributor.authorChan, Bun
dc.contributor.authorO'Reilly, Robert J
dc.contributor.authorEaston, Christopher
dc.contributor.authorRadom, Leo
dc.date.accessioned2015-12-10T23:01:32Z
dc.identifier.issn0022-3263
dc.identifier.urihttp://hdl.handle.net/1885/61650
dc.description.abstractIn recent computational studies of hydrogen-atom abstraction from amino acid derivatives, two distinct rationalizations have been put forward for the relative inertness of the α-C-H. Of these, the proposal that the inertness is due to a "kinetic trap" as
dc.publisherAmerican Chemical Society
dc.sourceJournal of Organic Chemistry
dc.subjectKeywords: Amino acid derivatives; Computational studies; Hydrogen abstraction; Kinetic traps; Polar effect; Stable complexes; Amino acids; Hydrogen; Abstracting; amide; amino acid derivative; chloride; hydrogen; hydroxide; article; chemical interaction; chemical re
dc.titleReactivities of amino acid derivatives toward hydrogen abstraction by Cl• and OH•
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume77
dc.date.issued2012
local.identifier.absfor030501 - Free Radical Chemistry
local.identifier.ariespublicationu4005981xPUB628
local.type.statusPublished Version
local.contributor.affiliationChan, Bun, University of Sydney
local.contributor.affiliationO'Reilly, Robert J, University of Sydney
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationRadom, Leo, University of Sydney
local.description.embargo2037-12-31
local.bibliographicCitation.issue21
local.bibliographicCitation.startpage9807
local.bibliographicCitation.lastpage9812
local.identifier.doi10.1021/jo3021538
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:25:24Z
local.identifier.scopusID2-s2.0-84868372241
local.identifier.thomsonID000311190200040
CollectionsANU Research Publications

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