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Synthesis of conjugated diene complexes of ruthenium(0) derived from Ru(η6-naphthalene)(η4-1,5-COD): Z to E isomerisation of coordinated 1,3-pentadiene

Hirano, Masafumi; Sakate, Yumiko; Inoue, Haruka; Arai, Yasutomo; Komine, Nobuyuki; Komiya, Sanshiro; Wang, Xian-qi; Bennett, Martin


The naphthalene complex of zerovalent ruthenium, [Ru(η6- C10H8)(η4-1,5-COD)] (1), readily reacts with 1,3-dienes in the presence of a ligand (L) to produce complexes [Ru(η4-cisoid-1,3-diene)(η4-1,5-COD)(L)] [1,3-diene = butadiene, 2,3-dimethylbutadien

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2012.02.018


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