Syntheses, structural, theoretical, and nonlinear optical studies of non-interpenetrating three-dimensional nest-shaped-cluster [MoOS 3 Cu 3 ]-based coordination polymers
Zhang, Jinfang; Meng, Suci; Song, Yinglin; Zhou, Yimeng; Cao, Yuan; Li, Jianghua; Zhao, Huajian; Hu, Jingchun; Wu, Jinhua; Humphrey, Mark; Zhang, Chi
Description
An efficient route to construct three-dimensional (3-D) M/S/Cu nest-cluster-based coordination polymers has been developed. By this method, cyanide bridges have been successfully introduced to build three new non-interpenetrating 3-D nest-shaped-cluster [MoOS3Cu 3]-based coordination polymers, 3∞{[(NO3)⊂(Me4N)3] ⊂[MoOS3Cu3(CN)3]} (1) and 3∞{[(NH4)·2DMF]⊂[Mo2O 2S6Cu6(CN)3(L)4]} (L 1 = bipy = 4,4′-bipyridine, 2; L2 = bpee = 1,2-bis(4-pyridyl)ethene, 3). The structures of 1-3 have been established...[Show more]
Collections | ANU Research Publications |
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Date published: | 2011 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/61160 |
Source: | Crystal Growth & Design |
DOI: | 10.1021/cg1009779 |
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01_Zhang_Syntheses,_structural,_2011.pdf | 1.24 MB | Adobe PDF | Request a copy |
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