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Group 14 substituted carbyne complexes - an almost complete set: [Mo(≡CAPh 3 )(CO) 2 (Tp*)] (Tp* = hydrotris(dimethylpyrazolyl)borate; A = Si, Ge, Sn, Pb but A ≠ C).

Cordiner, Richard; Hill, Anthony; Shang, Rong; Willis, Anthony

Description

The successive reactions of [Mo(≡CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and ClAPh3 (A = Ge, Sn, Pb) afford the carbyne complexes [Mo(≡CAPh3)(CO)2(Tp*)] but fail in the case of ClCPh3 and ClSiPh3. The silicon analo

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/61043
Source: Organometallics
DOI: 10.1021/om100896r

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