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Variation in both metal and ligand frontier orbital levels in series of [RuCl 6-n (PrCN) n ] z (n = 0-6) complexes

Billones, Junie B; Ratilla, Eva Marie A; Heath, Graham


An extensive series of butyronitrile-substituted ruthenium chloride complexes [RuCl6 - nLn]z (n = 0-6; L CH3(CH2)2CN or PrCN) has been prepared and characterized spectro-electrochemically. The complete series allowed the examination of the variation in electrode potential of RuIII/II couple and the accompanying trends in both Cl → Ru(III) and Ru(II) → PrCN charge-transfer spectra. Systematic analysis of electrochemical and spectroscopic data led to a conceptual representation of the relative...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Inorganic Chemistry Communications
DOI: 10.1016/j.inoche.2011.08.010


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