Skip navigation
Skip navigation

Variation in both metal and ligand frontier orbital levels in series of [RuCl 6-n (PrCN) n ] z (n = 0-6) complexes

Billones, Junie B; Ratilla, Eva Marie A; Heath, Graham

Description

An extensive series of butyronitrile-substituted ruthenium chloride complexes [RuCl6 - nLn]z (n = 0-6; L CH3(CH2)2CN or PrCN) has been prepared and characterized spectro-electrochemically. The complete series allowed the examination of the variation in electrode potential of RuIII/II couple and the accompanying trends in both Cl → Ru(III) and Ru(II) → PrCN charge-transfer spectra. Systematic analysis of electrochemical and spectroscopic data led to a conceptual representation of the relative...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/60987
Source: Inorganic Chemistry Communications
DOI: 10.1016/j.inoche.2011.08.010

Download

File Description SizeFormat Image
01_Billones_Variation_in_both_metal_and_2011.pdf536.64 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  20 July 2017/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator