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Organometallic macrocyclic chemistry. 8: an unusual metallacycle derived from phosphine-alkynyl thioether coupling

Hill, Anthony; Niess, Barbara; Schultz, Madeleine; White, Andrew J P; Williams, David


The α,ω-diyne 4,7,10-trithiatrideca-2,11-diyne reacts with [RuCl2(PPh3)3] and KPF6 to form the phosphonio-substituted metallatricyclic salt [RuCl(PPh3) {κ4C,S,S′,S″-S(C≡CMe)C2H4SC2H4SC(PPh3)CMe}]PF6 arising from the activation of one alkynyl grou

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Organometallics
DOI: 10.1021/om100835r


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