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Synthesis of a thiocarbamoyl alkylidyne complex and caveats associated with the use of [Mo(≡CLi)(CO) 2 (Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)

Colebatch, Annie; Hill, Anthony; Shang, Rong; Willis, Anthony

Description

The successive reactions of [Mo(≡CBr)(CO)2(Tp*)] (1; Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and N,N′-dimethylthiocarbamoyl chloride provides as intended, via formation of [Mo(≡CLi)(CO)2(Tp*)] (2a), the thiocarbamoyl alkylidyne c

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
URI: http://hdl.handle.net/1885/60877
Source: Organometallics
DOI: 10.1021/om1008296

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