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Alkynyl selenolate complexes of iron, nickel, and molybdenum.

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Caldwell, Lorraine; Hill, Anthony; Hulkes, Alexander; McQueen, Caitlin; White, Andrew J P; Williams, David

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The successive treatment of terminal alkynes, HC≡CR (R = C6H4Me-4, SiMe3), withnBuLi and gray selenium affords LiSeC≡CR, which in turn reacts with [FeCl(CO)2(η-C5H5)], [NiCl(PPh3)(η- C5H5)], and [MoI(CO)3(η-C5H5)] to afford the alkynylselenolato co

dc.contributor.authorCaldwell, Lorraine
dc.contributor.authorHill, Anthony
dc.contributor.authorHulkes, Alexander
dc.contributor.authorMcQueen, Caitlin
dc.contributor.authorWhite, Andrew J P
dc.contributor.authorWilliams, David
dc.date.accessioned2015-12-10T22:58:25Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/60848
dc.description.abstractThe successive treatment of terminal alkynes, HC≡CR (R = C6H4Me-4, SiMe3), withnBuLi and gray selenium affords LiSeC≡CR, which in turn reacts with [FeCl(CO)2(η-C5H5)], [NiCl(PPh3)(η- C5H5)], and [MoI(CO)3(η-C5H5)] to afford the alkynylselenolato co
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Alkynyls; Electrophiles; Low-yield; Terminal alkyne; Acetylene; Iron compounds; Molybdenum; Molybdenum compounds; Selenium; Chromium compounds
dc.titleAlkynyl selenolate complexes of iron, nickel, and molybdenum.
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume29
dc.date.issued2010
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationU4217927xPUB568
local.type.statusPublished Version
local.contributor.affiliationCaldwell, Lorraine, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHulkes, Alexander, Imperial College London
local.contributor.affiliationMcQueen, Caitlin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhite, Andrew J P, Imperial College London
local.contributor.affiliationWilliams, David, Imperial College London
local.description.embargo2037-12-31
local.bibliographicCitation.issue23
local.bibliographicCitation.startpage6350
local.bibliographicCitation.lastpage6358
local.identifier.doi10.1021/om100694f
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:44:15Z
local.identifier.scopusID2-s2.0-78649876283
local.identifier.thomsonID000284866000026
CollectionsANU Research Publications

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