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Alkynyl selenolate complexes of iron, nickel, and molybdenum.

Caldwell, Lorraine; Hill, Anthony; Hulkes, Alexander; McQueen, Caitlin; White, Andrew J P; Williams, David


The successive treatment of terminal alkynes, HC≡CR (R = C6H4Me-4, SiMe3), withnBuLi and gray selenium affords LiSeC≡CR, which in turn reacts with [FeCl(CO)2(η-C5H5)], [NiCl(PPh3)(η- C5H5)], and [MoI(CO)3(η-C5H5)] to afford the alkynylselenolato co

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Organometallics
DOI: 10.1021/om100694f


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