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Chiral Birch reduced tertiary phosphines: precursors to asymmetric 1,2-cyclohexenebis(tertiary phosphines)

Bulbrook, Michelle; Chu, Minghui; Deane, Karen; Doyle, Roy; Hinc, Justina; Petersen, Charlotte; Salem, Geoffrey; Thorman, Nadia; Willis, Anthony


The first examples of an optically active Birch reduced tertiary phosphine, viz. (RP)-(cyclohexa-2,5-dienyl)(3-pentyl)phenylphosphine, and successful hydrophosphination of the related racemic ligand (±)- (cyclohexa-2,5-dienyl)(2-propyl)phenylphosphine wi

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c0dt00648c


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