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Synthesis and Applications of Tricarbonyliron Complexes of Dendralenes

Toombs-Ruane, Henry; Osinski, Nik; Fallon, Thomas; Wills, Cindy; Willis, Anthony; Paddon-Row, Michael; Sherburn, Michael

Description

[3]Dendralene and [4]dendralene are converted smoothly into tricarbonyliron complexes. The structures of four complexes analyzed by DFT and single-crystal X-ray analysis show that, in contrast to free hydrocarbons, complexed dendralenes prefer a roughly in-plane conformation. The complexes are stable towards Fe(CO)3 group migration up to 150 °C. The synthetic value of Fe(CO)3 complexation in the dendralene series is demonstrated through a variety of selective synthetic manipulations...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/60565
Source: Chemistry - An Asian Journal
DOI: 10.1002/asia.201100455

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