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Five-Coordinate Hydrido-Ruthenium(II) Complexes Featuring N -Heterocyclic Silylene and Carbene Ligands

Cade, Ian; Hill, Anthony; Kamphe, Alex; Wagler, Jorg

Description

The reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H2)(PCy3)2] and IiPr.

dc.contributor.authorCade, Ian
dc.contributor.authorHill, Anthony
dc.contributor.authorKamphe, Alex
dc.contributor.authorWagler, Jorg
dc.date.accessioned2015-12-10T22:57:06Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/60513
dc.description.abstractThe reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H2)(PCy3)2] and IiPr.
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Carbene ligands; Co-ordinatively unsaturated; N-heterocyclic silylene; Ruthenium complexes; Silylenes; Ligands; Organic compounds; Ruthenium; Ruthenium compounds
dc.titleFive-Coordinate Hydrido-Ruthenium(II) Complexes Featuring N -Heterocyclic Silylene and Carbene Ligands
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume29
dc.date.issued2010
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB544
local.type.statusPublished Version
local.contributor.affiliationCade, Ian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationKamphe, Alex, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWagler, Jorg, Freiberg University of Mining and Technology
local.description.embargo2037-12-31
local.bibliographicCitation.issue18
local.bibliographicCitation.startpage4012
local.bibliographicCitation.lastpage4017
local.identifier.doi10.1021/om100146m
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:44:09Z
local.identifier.scopusID2-s2.0-77956937523
local.identifier.thomsonID000281831800004
CollectionsANU Research Publications

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