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Five-Coordinate Hydrido-Ruthenium(II) Complexes Featuring N -Heterocyclic Silylene and Carbene Ligands

Cade, Ian; Hill, Anthony; Kamphe, Alex; Wagler, Jorg


The reactions of [RuCl2(=CHPh)(PCy3)2] or [RuHCl(=-H2)(PCy3)2] with the N-heterocyclic silylene:Si(NtBuCH)2 (ISitBu) affords the coordinatively unsaturated silylene complex [RuHCl(ISitBu)(PCy3)2]. For comparative purposes, the corresponding complex [RuHCl(IiPr)(PCy3)2] (IiPr =:C(NiPrCH)2) was obtained from [RuHCl(ν-H2)(PCy3)2] and IiPr.

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Organometallics
DOI: 10.1021/om100146m


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