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First determination of the rate constant for ring-closure of an azahexenoyl radical: 6-aza-7-ethyl-5-hexenoyl

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Kyne, Sarah H; Lin, Ching-Yeh; Ryu, Ilhyong; Coote, Michelle; Schiesser, Carl

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Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estimate for the rate constant for 6-endo cyclization of the 6-aza-7-ethyl-5-hexenoyl radical of (4.8 ± 2.4) × 10 6 s-1 at 90° C in benzene, in good agreemen

dc.contributor.authorKyne, Sarah H
dc.contributor.authorLin, Ching-Yeh
dc.contributor.authorRyu, Ilhyong
dc.contributor.authorCoote, Michelle
dc.contributor.authorSchiesser, Carl
dc.date.accessioned2015-12-10T22:56:47Z
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/60374
dc.description.abstractCompetitive kinetic experiments utilising free radical carbonylation chemistry provide a first estimate for the rate constant for 6-endo cyclization of the 6-aza-7-ethyl-5-hexenoyl radical of (4.8 ± 2.4) × 10 6 s-1 at 90° C in benzene, in good agreemen
dc.publisherRoyal Society of Chemistry
dc.sourceChemical Communications
dc.subjectKeywords: benzene; radical; article; calculation; carbonylation; chemical analysis; chemical structure; cyclization; gas chromatography; kinetics; Aza Compounds; Cyclization; Free Radicals; Kinetics; Molecular Conformation
dc.titleFirst determination of the rate constant for ring-closure of an azahexenoyl radical: 6-aza-7-ethyl-5-hexenoyl
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume46
dc.date.issued2010
local.identifier.absfor030501 - Free Radical Chemistry
local.identifier.absfor030701 - Quantum Chemistry
local.identifier.ariespublicationu4217927xPUB536
local.type.statusPublished Version
local.contributor.affiliationKyne, Sarah H, University of Melbourne
local.contributor.affiliationLin, Ching-Yeh, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationRyu, Ilhyong, Osaka University
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSchiesser, Carl, University of Melbourne
local.description.embargo2037-12-31
local.bibliographicCitation.issue35
local.bibliographicCitation.startpage6521
local.bibliographicCitation.lastpage6523
local.identifier.doi10.1039/c0cc01262a
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:44:07Z
local.identifier.scopusID2-s2.0-77956020759
local.identifier.thomsonID000281237600027
CollectionsANU Research Publications

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