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First determination of the rate constant for ring-closure of an azahexenoyl radical: 6-aza-7-ethyl-5-hexenoyl

Kyne, Sarah H; Lin, Ching-Yeh; Ryu, Ilhyong; Coote, Michelle; Schiesser, Carl


Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estimate for the rate constant for 6-endo cyclization of the 6-aza-7-ethyl-5-hexenoyl radical of (4.8 ± 2.4) × 10 6 s-1 at 90° C in benzene, in good agreemen

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Chemical Communications
DOI: 10.1039/c0cc01262a


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