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A computational study of the radical ring-opening polymerization of diphosphetanes

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Coote, Michelle; Namazian, Mansoor; Wild, Stanley (Bruce)

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Radical ring-opening of four-membered 1,3-diphosphetanes appears to be a facile process of similar propensity and mechanism to that of the parent phosphetanes, but the greater kinetic stability of the diphosphetanes could make them more attractive precursors for polymerization.

dc.contributor.authorCoote, Michelle
dc.contributor.authorNamazian, Mansoor
dc.contributor.authorWild, Stanley (Bruce)
dc.date.accessioned2015-12-10T22:56:29Z
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/60256
dc.description.abstractRadical ring-opening of four-membered 1,3-diphosphetanes appears to be a facile process of similar propensity and mechanism to that of the parent phosphetanes, but the greater kinetic stability of the diphosphetanes could make them more attractive precursors for polymerization.
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Computational studies; Kinetic stability; Radical ring; Radical ring opening polymerization; Ring opening polymerization
dc.titleA computational study of the radical ring-opening polymerization of diphosphetanes
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume63
dc.date.issued2010
local.identifier.absfor030299 - Inorganic Chemistry not elsewhere classified
local.identifier.absfor030701 - Quantum Chemistry
local.identifier.ariespublicationu4217927xPUB530
local.type.statusPublished Version
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationNamazian, Mansoor, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue8
local.bibliographicCitation.startpage1189
local.bibliographicCitation.lastpage1194
local.identifier.doi10.1071/CH10085
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:44:04Z
local.identifier.scopusID2-s2.0-77955667906
local.identifier.thomsonID000280727900010
CollectionsANU Research Publications

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