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An Unusually Flexible Expanded Hexaamine Cage and Its Cu II Complexes: Variable Coordination Modes and Incomplete Encapsulation

Qin, Chang; James, Lloyd; Chartres, Jy D; Alcock, Leighton J; Davis, Kimberley J; Willis, Anthony; Sargeson, Alan; Bernhardt, Paul; Ralph, Stephen F


The bicyclic hexaamine "cage" ligand Me 8tricosaneN6 (1,5,5,9,13,13,20,20-octamethyl-3,7,11,15,18, 22-hexaazabicyclo[7.7.7]tricosane) is capable of encapsulating octahedral metal ions, yet its expanded cavity allows the complexed metal to adopt a variety

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic201326d


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