First measurements of 236 U concentrations and 236 U/ 239 Pu isotopic ratios in a Southern Hemisphere soil far from nuclear test or reactor sites

Abstract

The variation of the 236U and 239Pu concentrations as a function of depth has been studied in a soil profile at a site in the Southern Hemisphere well removed from nuclear weapon test sites. Total inventories of 236U and 239Pu as well as the 236U/239Pu isotopic ratio were derived. For this investigation a soil core from an undisturbed forest area in the Herbert River catchment (17°30' - 19°S) which is located in north-eastern Queensland (Australia) was chosen. The chemical separation of U and Pu was carried out with a double column which has the advantage of the extraction of both elements from a relatively large soil sample (~20g) within a day. The samples were measured by Accelerator Mass Spectrometry using the 14UD pelletron accelerator at the Australian National University. The highest atom concentrations of both 236U and 239Pu were found at a depth of 2-3cm. The 236U/239Pu isotopic ratio in fallout at this site, as deduced from the ratio of the 236U and 239Pu inventories, is 0.085±0.003 which is clearly lower than the Northern Hemisphere value of ~0.2. The 236U inventory of (8.4±0.3)×1011 at/m2 was more than an order of magnitude lower than values reported for the Northern Hemisphere. The 239Pu activity concentrations are in excellent agreement with a previous study and the 239+240Pu inventory was (13.85±0.29)Bq/m2. The weighted mean 240Pu/239Pu isotopic ratio of 0.142±0.005 is slightly lower than the value for global fallout, but our results are consistent with the average ratio of 0.173±0.027 for the southern equatorial region (0-30°S).