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Organometallic Complexes for Nonlinear Optics, 47 - Synthesis and Cubic Optical Nonlinearity of a Stilbenylethynylruthenium Dendrimer

Jeffery, Christopher; Cifuentes, Marie; Dalton, Gulliver; Corkery, Timothy; Randles , Michael; Willis, Anthony; Samoc, Marek; Humphrey, Mark

Description

(Figure Presented) The synthesis of the 1st generation dendrimer l,3,5-{trans-[Ru(C=C-3,5-(trans-[Ru(C= CPh)(dppe)2(C=CC 6H4-4-(E)-CH=CH)] )2C6H 3)(dppe)2(C=CC6H4-4-(E)-CH=CH)] }3C6H3 proceeds by a novel route that features Emmons-Horner-Wadsworth coupling of 1,3,5-C6H3(CH 2PO(OEt)2)3 with trans-[Ru(C≡CC 6H4-4CHO)Cl(dppe)2] and 1-I-C6H 3-3,5-(CH2PO(OEt)2)2 with trans-[Ru(C≡CPh)(C≡CC6H4-4-CHO)(dppe) 2] as key steps. The stilbenylethynylruthenium dendrimer is much more soluble than its...[Show more]

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
URI: http://hdl.handle.net/1885/59885
Source: Macromolecular Rapid Communications
DOI: 10.1002/marc.200900859

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