Dodecanuclear-Ellipse and Decanuclear-Wheel Nickel(II) Thiolato Clusters with Efficient Femtosecond Nonlinear Absorption
Zhang, Chi; Matsumoto, Tsuyosh; Samoc, Marek; Petrie, Simon; Meng, Suci; Corkery, Timothy; Stranger, Robert; Zhang, Jinfang; Tatsumi, Kazuyuki; Humphrey, Mark
(Figure Presented) Crowned with success: Stepwise coordination of two kinds of thiolate ligands to a nickel (II) center affords a dodecanuclear ellipse (see structure) and two decanuclear wheel-like NiII-thiolato clusters. The wavelength-dependent nonlinear optical behavior of these tiara-like compounds was investigated and supported by theoretical studies. The results suggest that Ni-S π bonds play a crucial role.
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