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A Bridging Selenoacyl Complex via Alkynylselenolatoalkylidyne Rearrangement

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Caldwell, Lorraine; Cordiner, Richard; Hill, Anthony; Wagler, Jorg

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The alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe 3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ--SeCC-CSi

dc.contributor.authorCaldwell, Lorraine
dc.contributor.authorCordiner, Richard
dc.contributor.authorHill, Anthony
dc.contributor.authorWagler, Jorg
dc.date.accessioned2015-12-10T22:54:02Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/59617
dc.description.abstractThe alkynylselenolatoalkylidyne complex [Mo(-C-Se-C-CSiMe 3)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) reacts with [RhCl(PPh3)3] via an unusual C-Se bond cleavage/formation sequence to provide the heterodinuclear bridging selenoacyl complex [MoRh(μ--SeCC-CSi
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Crystal structure; Hysteresis motors; Rhodium compounds; Molybdenum compounds
dc.titleA Bridging Selenoacyl Complex via Alkynylselenolatoalkylidyne Rearrangement
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume29
dc.date.issued2010
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB500
local.type.statusPublished Version
local.contributor.affiliationCaldwell, Lorraine, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCordiner, Richard, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWagler, Jorg, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue7
local.bibliographicCitation.startpage1526
local.bibliographicCitation.lastpage1529
local.identifier.doi10.1021/om901079n
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:43:49Z
local.identifier.scopusID2-s2.0-77950824629
local.identifier.thomsonID000276215100005
CollectionsANU Research Publications

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