Cyclic enones as substrates in the Morita-Baylis-Hillman reaction: surfactant interactions, scope and scalability with an emphasis on formaldehyde
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Schwartz, Brett; Porzelle, Achim; Jack, Kevin S; Faber, Jonathan M; Gentle, Ian Ross; Williams, Craig
Description
Traditionally, cyclic enones and formalin are reactants notorious for displaying problematic behaviour (i.e., poor solubility and low yields) under Morita-Baylis-Hillman (MBH) reaction conditions. The body of research presented herein focuses on the use of surfactants in water as a solvent medium that offers a resolution to many of the issues associated with the MBH reaction. Reaction scope, scalability and small angle X-ray scattering have been studied to assist with the understanding of the...[Show more]
dc.contributor.author | Schwartz, Brett | |
---|---|---|
dc.contributor.author | Porzelle, Achim | |
dc.contributor.author | Jack, Kevin S | |
dc.contributor.author | Faber, Jonathan M | |
dc.contributor.author | Gentle, Ian Ross | |
dc.contributor.author | Williams, Craig | |
dc.date.accessioned | 2015-12-10T22:54:01Z | |
dc.identifier.issn | 1615-4150 | |
dc.identifier.uri | http://hdl.handle.net/1885/59613 | |
dc.description.abstract | Traditionally, cyclic enones and formalin are reactants notorious for displaying problematic behaviour (i.e., poor solubility and low yields) under Morita-Baylis-Hillman (MBH) reaction conditions. The body of research presented herein focuses on the use of surfactants in water as a solvent medium that offers a resolution to many of the issues associated with the MBH reaction. Reaction scope, scalability and small angle X-ray scattering have been studied to assist with the understanding of the reaction mechanism and industrial application. A comparison against known literature methods for reaction scale-up is also discussed. | |
dc.publisher | Wiley-VCH Verlag GMBH | |
dc.source | Advanced Synthesis & Catalysis | |
dc.subject | Keywords: Cyclic enones; Morita-Baylis-Hillman reaction; Small angle X-ray scattering (SAXS); Surfactants | |
dc.title | Cyclic enones as substrates in the Morita-Baylis-Hillman reaction: surfactant interactions, scope and scalability with an emphasis on formaldehyde | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 351 | |
dc.date.issued | 2009 | |
local.identifier.absfor | 030502 - Natural Products Chemistry | |
local.identifier.ariespublication | u4005981xPUB500 | |
local.type.status | Published Version | |
local.contributor.affiliation | Schwartz, Brett, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Porzelle, Achim, University of Queensland | |
local.contributor.affiliation | Jack, Kevin S, University of Queensland | |
local.contributor.affiliation | Faber, Jonathan M, University of Queensland | |
local.contributor.affiliation | Gentle, Ian Ross, University of Queensland | |
local.contributor.affiliation | Williams, Craig, University of Queensland | |
local.description.embargo | 2037-12-31 | |
local.bibliographicCitation.issue | 7-8 | |
local.bibliographicCitation.startpage | 1148 | |
local.bibliographicCitation.lastpage | 1154 | |
local.identifier.doi | 10.1002/adsc.200800739 | |
local.identifier.absseo | 970103 - Expanding Knowledge in the Chemical Sciences | |
dc.date.updated | 2016-02-24T10:24:30Z | |
local.identifier.scopusID | 2-s2.0-66149100871 | |
Collections | ANU Research Publications |
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