Total Synthesis of (±)-Vibsanin E
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Schwartz, Brett; Denton, Justin R; Davies, Huw ML; Williams, Craig
Description
Vibsanin E (1), a structurally rare complex diterpene, consisting of a compact 3-oxatricyclo[6.3.2.05,10] tridecane core and an unprecedented 3,3-dimethylacroyl enol ester functional group, formulate a considerable synthetic challenge. Williams and Davies failed to independently synthesize this nemesis, however, a 'two heads are better than one' approach delivered the first total synthesis of the molecule, since its diamond aniversary isolation.
Collections | ANU Research Publications |
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Date published: | 2009 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/59576 |
Source: | Australian Journal of Chemistry |
DOI: | 10.1071/CH09267 |
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