Mobilization of Fine Particles during Flooding of Sandstones and Possible Relations to Enhanced Oil Recovery

Abstract

The mounting evidence that waterflooding of clay-containing sandstone reservoirs using floodwater with reduced salinity can enhance oil recovery, but with unpredictably large variation in responses, demands improved understanding of the underlying mechanisms. Mobilization of clays and other fines is one candidate mechanism. Flow experiments in Berea sandstone plugs were designed such that the change in their fines distribution from before to after the oil and water injections could be imaged in exactly the same pores using scanning electron microscopy. This technique also allowed imaging of the wettability distribution on pore surfaces and was coupled to spectroscopic analysis of the adsorbed asphaltene amounts. One-phase flows switching from high- to low-salinity water led to only a low level of fines mobilization, compared to two-phase experiments in which high- or low-salinity water displaced crude oil from mixed-wet prepared plugs. The images reveal that loosely bound, partially oil-wet fines lining sandstone grains are stripped by the adhering oil during its recovery and redeposited on grains further downstream. Reduced salinity increases the fraction of fines thus mobilized by weakening their bonds to grains and strengthening their bonds to oil. Evidence suggests that these more oil-wet fines stabilize the water-in-oil curved menisci, which can aid in maintaining the connectivity of the oil phase and thus enhance oil recovery.