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Bidentate chelate complexes of palladium(II) with the carbanion 2-C 6 F 4 PPh 2 and their transformation into complexes containing bridging 2-C 6 F 4 PPh 2

Bennett, Martin; Kar, Gopa; Mirzadeh, Nedaossadat; Priver, Steven H; Rae, A David; Wagler, Jorg; Willis, Anthony; Bhargava, Suresh Kumar

Description

Reaction of the organotin compound 2-Me3SnC6F 4PPh2 (7) with the cycloocta-1,5-diene complexes [PdX 2(cod)] at room temperature gives dinuclear halide-bridged palladium(II) complexes [Pd2(μ-X)2(κ2- 2-C6F4PPh2)2] [X = Cl (5), Br (8)] in which the carbani

dc.contributor.authorBennett, Martin
dc.contributor.authorKar, Gopa
dc.contributor.authorMirzadeh, Nedaossadat
dc.contributor.authorPriver, Steven H
dc.contributor.authorRae, A David
dc.contributor.authorWagler, Jorg
dc.contributor.authorWillis, Anthony
dc.contributor.authorBhargava, Suresh Kumar
dc.date.accessioned2015-12-10T22:53:10Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/59236
dc.description.abstractReaction of the organotin compound 2-Me3SnC6F 4PPh2 (7) with the cycloocta-1,5-diene complexes [PdX 2(cod)] at room temperature gives dinuclear halide-bridged palladium(II) complexes [Pd2(μ-X)2(κ2- 2-C6F4PPh2)2] [X = Cl (5), Br (8)] in which the carbani
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Acetylacetonates; Bidentate chelates; Chelate ring; Cis-trans; Dinuclear; Dinuclear complex; Four-membered chelate rings; Organotin compound; Palladium complexes; Ring opening; Room temperature; X-ray structure; Acetonitrile; Chelation; Negative ions; Ole
dc.titleBidentate chelate complexes of palladium(II) with the carbanion 2-C 6 F 4 PPh 2 and their transformation into complexes containing bridging 2-C 6 F 4 PPh 2
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume30
dc.date.issued2011
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4005981xPUB480
local.type.statusPublished Version
local.contributor.affiliationBennett, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationKar, Gopa, RMIT University
local.contributor.affiliationMirzadeh, Nedaossadat, RMIT University
local.contributor.affiliationPriver, Steven H, RMIT University
local.contributor.affiliationRae, A David, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWagler, Jorg, Freiberg University of Mining and Technology
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBhargava, Suresh Kumar, RMIT University
local.description.embargo2037-12-31
local.bibliographicCitation.issue14
local.bibliographicCitation.startpage3749
local.bibliographicCitation.lastpage3762
local.identifier.doi10.1021/om200179v
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T10:24:23Z
local.identifier.scopusID2-s2.0-79960528280
local.identifier.thomsonID000292847900010
CollectionsANU Research Publications

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