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Bidentate chelate complexes of palladium(II) with the carbanion 2-C 6 F 4 PPh 2 and their transformation into complexes containing bridging 2-C 6 F 4 PPh 2

Bennett, Martin; Kar, Gopa; Mirzadeh, Nedaossadat; Priver, Steven H; Rae, A David; Wagler, Jorg; Willis, Anthony; Bhargava, Suresh Kumar

Description

Reaction of the organotin compound 2-Me3SnC6F 4PPh2 (7) with the cycloocta-1,5-diene complexes [PdX 2(cod)] at room temperature gives dinuclear halide-bridged palladium(II) complexes [Pd2(μ-X)2(κ2- 2-C6F4PPh2)2] [X = Cl (5), Br (8)] in which the carbani

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/59236
Source: Organometallics
DOI: 10.1021/om200179v

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