Tuning the Laplaza-Cummins 3-coordinate M[N(R)Ph] 3 catalyst to activate and cleave CO 2
The Laplaza-Cummins catalyst L3Mo (L = N(R)Ar), is experimentally inactive towards carbon dioxide. Previous theoretical analysis identified the cause for this inactivity and suggested that a switch to a d2 transition metal may induce activity towards the
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