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Nano- and Microstructure of High-Internal Phase Emulsions Under Shear

Yaron, Peter; Reynolds, Philip; McGillivray, Duncan J; Jitendrakumar, Mata; White, John


High-internal phase aqueous-in-oil emulsions of two surfactant concentrations were studied using smallangle neutron scattering (SANS) and simultaneous in situ rheology measurements. They contained a continuous oil phase with differing amounts of hexadecane and d-hexadecane (for contrast matching experiments), a deuteroaqueous phase almost saturated with ammonium nitrate, and an oil-soluble stabilizing polyisobutylenebased surfactant. The emulsions' macroscopic Theological behavior has been...[Show more]

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Journal of Physical Chemistry B
DOI: 10.1021/jp9084525


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