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Studies Directed Towards the Preparation of Probes for the Photoaffinity Labelling of Gibberellin Receptors

Crow, James; Chandler, Peter; Mander, Lewis

Description

Model studies for the preparation of photoaffinity probes designed to explore the nature of gibberellin receptor sites have provided a wide range of gibberellin derivatives that should afford useful scaffolds incorporating auxiliary groups attached to C-2 and C-12. Methodology features the stereocontrolled opening of 2β,3β-epoxy gibberellins by attack on the lower face at C-2, while functionalization of C-12 was effected by the rhodium acetate-catalyzed CH insertion reaction of a 17-diazo...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/58524
Source: Australian Journal of Chemistry
DOI: 10.1071/CH10441

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