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Arsenicin A, A Natural Polyarsenical: Synthesis and Crystal Structure

Lu, Di; Rae, A David; Salem, Geoffrey; Weir, Michelle; Willis, Anthony; Wild, Stanley (Bruce)


The synthesis of the natural polyarsenical Arsenicin A and its crystal structure are described. The molecule has the adamantane-type structure of arsenic trioxide in which three of the oxygen atoms have been replaced by methylene groups to generate four arsenic stereocenters of the same configuration in each enantiomer of the racemate.

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Organometallics
DOI: 10.1021/om900998q


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