Iridium-Molybdenum Carbido Complex via C-Se Activation of a Selenocarbonyl Ligand:(μ-Se 2 )[Ir 2 {C≡Mo(CO) 2 (Tp*)} 2 (CO) 2 (PPh 3 ) 2 ] (Tp*= hydrotris(dimethylpyrazolyl)borate)

Cade, Ian; Hill, Anthony; McQueen, Caitlin

doi:10.1021/om9008873

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Iridium-Molybdenum Carbido Complex via C-Se Activation of a Selenocarbonyl Ligand:(μ-Se 2 )[Ir 2 {C≡Mo(CO) 2 (Tp)} 2 (CO) 2 (PPh 3 ) 2 ] (Tp= hydrotris(dimethylpyrazolyl)borate)

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Cade, Ian; Hill, Anthony; McQueen, Caitlin

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The reaction of [Et4N][Mo(CSe)(CO)2(Tp*))] (Tp* = hydrotris(dimethylpyrazolyl)borate) with [Ir(NCMe) (CO) (PPh 3)2]BF4 results not in the anticipated isoselenocarbonyl complex [(Tp*) (CO)2Mo-CSe-Ir(CO) (PPh 3)2] but rather in the tetranuclear bis(μ-carbi

dc.contributor.author	Cade, Ian
dc.contributor.author	Hill, Anthony
dc.contributor.author	McQueen, Caitlin
dc.date.accessioned	2015-12-10T22:44:08Z
dc.identifier.issn	0276-7333
dc.identifier.uri	http://hdl.handle.net/1885/58466
dc.description.abstract	The reaction of [Et4N][Mo(CSe)(CO)2(Tp))] (Tp = hydrotris(dimethylpyrazolyl)borate) with [Ir(NCMe) (CO) (PPh 3)2]BF4 results not in the anticipated isoselenocarbonyl complex [(Tp*) (CO)2Mo-CSe-Ir(CO) (PPh 3)2] but rather in the tetranuclear bis(μ-carbi
dc.publisher	American Chemical Society
dc.source	Organometallics
dc.subject	Keywords: Iridium; Iridium compounds; Molybdenum; Molybdenum compounds
dc.title	Iridium-Molybdenum Carbido Complex via C-Se Activation of a Selenocarbonyl Ligand:(μ-Se 2 )[Ir 2 {C≡Mo(CO) 2 (Tp)} 2 (CO) 2 (PPh 3 ) 2 ] (Tp= hydrotris(dimethylpyrazolyl)borate)
dc.type	Journal article
local.description.notes	Imported from ARIES
local.identifier.citationvolume	28
dc.date.issued	2009
local.identifier.absfor	039904 - Organometallic Chemistry
local.identifier.ariespublication	u4217927xPUB443
local.type.status	Published Version
local.contributor.affiliation	Cade, Ian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliation	Hill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliation	McQueen, Caitlin, College of Physical and Mathematical Sciences, ANU
local.description.embargo	2037-12-31
local.bibliographicCitation.issue	23
local.bibliographicCitation.startpage	6639
local.bibliographicCitation.lastpage	6641
local.identifier.doi	10.1021/om9008873
dc.date.updated	2016-02-24T10:43:34Z
local.identifier.scopusID	2-s2.0-72049116868
local.identifier.thomsonID	000272560700007
Collections	ANU Research Publications

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Iridium-Molybdenum Carbido Complex via C-Se Activation of a Selenocarbonyl Ligand:(μ-Se 2 )[Ir 2 {C≡Mo(CO) 2 (Tp*)} 2 (CO) 2 (PPh 3 ) 2 ] (Tp*= hydrotris(dimethylpyrazolyl)borate)

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Iridium-Molybdenum Carbido Complex via C-Se Activation of a Selenocarbonyl Ligand:(μ-Se 2 )[Ir 2 {C≡Mo(CO) 2 (Tp)} 2 (CO) 2 (PPh 3 ) 2 ] (Tp= hydrotris(dimethylpyrazolyl)borate)