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Phosphino and Phosphonito Carbyne Complexes: [Mo(≡CX)(CO) 2 {HB(pzMe 2 ) 3 }] (X = PPh 2 , P(:O)(OEt) 2 ; pz = Pyrazol-1-yl).

Cordiner, Richard; Gugger, Paul; Hill, Anthony; Willis, Anthony


The phosphinocarbyne complex [Mo(≡CPPh2)(CO)2{HB(pzMe 2)3}] is obtained by successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe2)3}] with nBuLi and ClPPh2. An alternative approach to phosphorus-functionalized carbyne complexes involves the palladium-mediate

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Organometallics
DOI: 10.1021/om900868s


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