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Syntheses and NLO properties of 1D heterothiometallic anionic W/S/Ag clusters possessing solvento-ytterbium cation-directed isomeric skeletons

Zhang, Jinfang; Meng, Suci; Song, Yinglin; Yang, Junyi; Wei, Hongyang; Huang, Wenjiang; Cifuentes, Marie; Zhang, Chi; Humphrey, Mark


The sequential addition to [WS4]2- of different solvent-coordinated ytterbium cations as templates and silver iodide as Ag + source afforded the heterothiometallic clusters {[Yb(DMSO) 7][Yb(DMSO)8][W6S24Ag 6]}n1 (DMSO = dimethyl sulfoxide), {[Yb(DMF) 8][W3S12Ag3]}n2 (DMF = N,N′-dimethylformamide) and {[Yb(HMP)4(NO3) 2][WS4Ag]}n3 (HMP = hexamethylphosphoramide) with isomeric anionic skeletons and in high yields. 1-3 have been fully characterized by elemental analysis, IR and UV-vis...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: New Journal of Chemistry
DOI: 10.1039/C0NJ00674B


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