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Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls

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Crossley, Ian R; Hill, Anthony; Willis, Anthony

Description

The iridium poly(methimazolayl)borane complexes [IrH(CE)(PPh3) {κ3-B,S,S-B(mt)2R}](Ir→B) (mt = methimazolyl = 2-mercapto-3-methylimidazol-l-yl; E = O, S; R = mt, H) are described in detail. For R = mt, these materials are elucidated as paradigms for th

dc.contributor.authorCrossley, Ian R
dc.contributor.authorHill, Anthony
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-10T22:43:57Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/58392
dc.description.abstractThe iridium poly(methimazolayl)borane complexes [IrH(CE)(PPh3) {κ3-B,S,S-B(mt)2R}](Ir→B) (mt = methimazolyl = 2-mercapto-3-methylimidazol-l-yl; E = O, S; R = mt, H) are described in detail. For R = mt, these materials are elucidated as paradigms for th
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Alternative routes; Borane complexes; Borate complexes; Chlorinated solvent; Hydride abstraction; Metal carbonyl; Metallaboratranes; Phase conversion; Carbonylation; Dyes; Hysteresis motors; Iridium; Iridium compounds; Rhodium; Rhodium compounds
dc.titleMetallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume29
dc.date.issued2010
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB440
local.type.statusPublished Version
local.contributor.affiliationCrossley, Ian R, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue2
local.bibliographicCitation.startpage326
local.bibliographicCitation.lastpage336
local.identifier.doi10.1021/om900655k
dc.date.updated2016-02-24T10:43:32Z
local.identifier.scopusID2-s2.0-74549195520
local.identifier.thomsonID000273618600008
CollectionsANU Research Publications

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