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Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls

Crossley, Ian R; Hill, Anthony; Willis, Anthony


The iridium poly(methimazolayl)borane complexes [IrH(CE)(PPh3) {κ3-B,S,S-B(mt)2R}](Ir→B) (mt = methimazolyl = 2-mercapto-3-methylimidazol-l-yl; E = O, S; R = mt, H) are described in detail. For R = mt, these materials are elucidated as paradigms for th

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Organometallics
DOI: 10.1021/om900655k


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