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Structural disorder, polarisation and the normal to relaxor ferroelectric transition in BaTiO 3 based perovskites

Liu, Yun; Withers, Raymond


This paper uses structured diffuse scattering to compare and contrast the local crystal structure behaviour of the normal ferroelectric BaTiO3 with a range of relaxor ferroelectric substituted BaTiO3 materials. The results strongly suggest that both normal ferroelectric BaTiO3 and the relaxor ferroelectric substituted BaTiO3's have the same underlying polarisation mechanism i.e. inherent 1-D correlated Ti cation and neighbouring O anion displacements forming 1-D dipole clusters (or polar nano...[Show more]

CollectionsANU Research Publications
Date published: 2010
Type: Journal article
Source: Ferroelectrics
DOI: 10.1080/00150191003697039


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