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Stoichiometric Regio- and Stereoselective Oxidative Coupling Reactions of Conjugated Dienes with Ruthenium(0). A Mechanistic Insight into the Origin of Selectivity

Hirano, Masafumi; Sakate, Yumiko; Komine, Nobuyuki; Komiya, Sanshiro; Wang, Xian-qi; Bennett, Martin


Treatment of [Ru(η6-C10H8) (η4-1,5-COD)] (1) with excess butadiene at room temperature produces supine,prone-[Ru(η3:η3-2,6-octadiene-1,8- diyl)( η4-1,5-COD)] (supine,prone-2). Similar treatment of 1 with isoprene and (E)-and (Z)-1,3-pentadiene also g

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/om100956f


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