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Unusual reactivity of the bis(pyrazolyl)borate Chelate: B-H for B-X (X = F, Cl, OH) Substitution in Complexes of Ruthenium

Page, Michael; Messerle, Barbara Ann; Wagler, Jorg

Description

Reaction of the complex [RuTp(Bp)PPh3] (6, where Tp = tris(pyrazolyl)borate and Bp = bis(pyrazolyl)borate) with AgBF4, AgOTf,and SOCl2 was observed to yield the highly unusual B-F- and B-OH-containing compounds [RuTp(BpF2)PPh3] (7), [RuTp(BpOH)PPh3]OTf (9), and [RuTp-(BpOH) PPh3]Cl (10), respectively, via substitution of the Bp boron-hydride groups. The complexes 7 and 9 were structurally characterized by X-ray crystallography. Formation of the B-F product 7 represents a rare example of BF4...[Show more]

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/58140
Source: Organometallics
DOI: 10.1021/om900660k

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