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Synthesis and properties of the ivyanes: the parent 1,1-oligocyclopropanes

Bojase-Moleta, Gomotsang; Nguyen, Thanh; Payne, Alan; Willis, Anthony; Sherburn, Michael

Description

Practical syntheses of the first six members of the ivyane (1,1-oligocyclopropane) family of fundamental hydrocarbons have been achieved from the cross-conjugated polyenes known as dendralenes. Evidence for helical conformations in both the solid state and in solution is presented. [6]Ivyane exhibits one of the highest experimental heats of combustion recorded for a hydrocarbon. Ring-opening reactions of ivyanes furnish new and interesting structures that are difficult to access by conventional...[Show more]

CollectionsANU Research Publications
Date published: 2011
Type: Journal article
URI: http://hdl.handle.net/1885/58011
Source: Chemical Science
DOI: 10.1039/C0SC00500B

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