Skip navigation
Skip navigation

Strongly Electron Deficient Sulfonyldithioformate Based RAFT Agents for Hetero Diels-Alder Conjugation: Computational Design and Experimental Evaluation

Nebhani, Leena; Sinnwell, Sebastian; Lin, Ching-Yeh; Coote, Michelle; Stenzel, Martina H; Barner-Kowollik, Christopher

Description

The synthesis of a novel class of reversible addition-fragmentation chain transfer (RAFT) agents-based on quantum-chemical ab initio calculations-having methylsulfonyl and phenylsulfonyl moieties as Z-group is described. The resulting C-sulfonyldithioformate transfer agents [benzyl methylsulfonyldithioformate (PSDTF) and benzyl phenylsulfonyldithioformate (PSDTF)] feature extremely strong electron deficient C=S double bonds and should thus be suitable to undergo rapid hetero Diels-Alder (HDA)...[Show more]

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
URI: http://hdl.handle.net/1885/57614
Source: Journal of Polymer Science: Part A: Polymer Chemistry
DOI: 10.1002/pola.23647

Download

File Description SizeFormat Image
01_Nebhani_Strongly_Electron_Deficient_2009.pdf275.63 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  23 August 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator